In this chapter you will learn how to: - relate a rise in temperature of an object to internal energy, the sum of the random distribution of kinetic and potential energies of the molecules in a system
- recall and use the first law of thermodynamics
- calculate the work done when the volume of a gas changes at constant pressure
- measure temperature using a physical property and state examples of such properties
- use the thermodynamic scale of temperature, and understand that the lowest possible temperature is zero kelvin and that this is known as absolute zero
- relate transfer of (thermal) energy as being due to a difference in temperature and understand thermal equilibrium
- define and use specific heat capacity and specific latent heat, and outline how these quantities can be measured.
BEFORE YOU START
- Write down the boiling point and melting point of water, and the names scientists use to describe changes of state (from solid to liquid, and from liquid to solid, and so on).
- List some difference between atoms and molecules. You can treat them both as simply ‘particles’ and not worry about how many atoms a molecule contains.
FROM WATER TO STEAM
When water boils, it changes state – it turns to water vapour. A liquid has become a gas. This is a familiar process, but Figure 19.1 shows a dramatic example of such a change of state. This is a geyser in New Zealand, formed when water is trapped underground where it is in contact with hot rocks. The temperature and pressure of the water build up until it suddenly erupts above the surface to form a tall plume of scalding water and water vapour. What happens underground to cause this effect? Would this be a useful effect to have happen near where you live?
Figure 19.1: At regular intervals of time, the White Lady Geyser, near Rotorua in New Zealand, throws up a plume of water (liquid) and water vapour (gas).
The kinetic model of matter can be used to describe the structure of solids, liquids and gases. You should recall that the kinetic model describes the behaviour of matter in terms of moving particles (atoms, molecules, and so on). Figure 19.2 should remind you of how we picture the three states of matter at the atomic scale:
- In a solid, the particles are close together, tightly bonded to their neighbours, and vibrating about fixed positions.
- In a gas, the particles have broken free from their neighbours; they are widely separated and are free to move around within their container.
Figure 19.2: Typical arrangements of atoms in a a solid, b a liquid and c a gas.
a
b
c
Question
1) Describe a liquid in terms of the arrangement of its particles, the bonding between them and their motion.
In this chapter, we will extend these ideas to look at the energy changes involved when materials are heated and cooled.