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Chemistry (A) H432/03 June 2022

Chemistry (A) H432/03 June 2022

1. Redox chemistry, electrode potentials, oxidation states in ammonium nitrate and dichromate, disproportionation of hypochlorite, redox titration with iodine and vitamin C, standard electrode potentials interpretation

2. Organic chemistry: nucleophilic substitution mechanism (1-bromobutane from butan-1-ol), reflux and distillation purification, structure–reactivity correlation in NMR, hydrogen bonding impact on boiling point, optical isomerism in vitamin C

3. Energetics: enthalpy change of hydration (Ca²⁺), calorimetry setup and calculation, Hess’s law energy cycle, combustion of fuel mixtures (octane + ethanol), entropy and enthalpy relationships

4. Equilibrium and Le Chatelier′s Principle: CoCl₄²⁻/Co(H₂O)₆²⁺ colorimetric analysis, effect of temperature and AgNO₃ on equilibrium shifts, graphical analysis of absorbance vs time

5. Polymer and amino acid chemistry: square planar copper(II) glycinate isomers, acid–base behavior of glycine salts and bond angle variations, formation and structure of amino acid complexes

6. Spectroscopic analysis and structural elucidation: ¹H and ¹³C NMR interpretation, splitting pattern prediction, chemical shift explanation, IR and mass spectrometry application for organic compound identification

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Classification: Paper 3
Page count: 20
Viewed: 31
Last update: 3 months ago
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